VRLA BATTERIES
The battery is an important
constituent of the Telecom Network for sustaining the trouble free and
uninterrupted service to its users. Till 1994, the whole of the Indian Telecom
Network relied wholly on Flooded type batteries to provide the necessary
Primary power back-up.
Moreover the Conventional
lead acid (Flooded type) batteries were being used in the department as primary
standby source.
Flooded
batteries were bulky and required a separate battery room with exhaust fans to
throw out the acid fumes emitted by these batteries.
Flooded
batteries can not be transported in charged condition, hence assembly and
charging at site is essential.
These
batteries also require periodical special charging process at comparatively
higher voltage of 2.7V/cell (a total voltage of 65 V), also known as
boost-charging, to agitate the electrolyte thoroughly to prevent stratification
of electrolyte, as well as to reduce sulpahtion of plates. As the telecom
equipment can not withstand such a high voltage, the battery under
boost-charging and the charger have to be isolated from the exchange equipment.
Maintenance
of these batteries needs more efforts and is more labour oriented.
Moreover,
it will be more difficult for the flooded batteries to meet the pollution
norms, issued by Ministry of Environment and Forest.
The electrode reactions in all lead acid batteries are
basically identical. As the battery discharges, the lead oxide (+ve active
material ) and spongy lead (-ve active material ) both react with sulphuric
acid ( Immobilized electrolyte ) to form lead sulphate and water. During
charging this process is reversed. At the end of charging oxygen gas evolved at
positive electrode & hydrogen gas is evolved at the negative electrode,
these gases make their way out and escape into environment, thereby losing
water. In VRLA batteries, the oxygen generated at positive plate is transported
in gaseous phase through the micro porous (AGM ) Absorbent Glass Mat separator
to the surface of negative plate. Due to oxygen recombination process, VRLA
battery do not lose water, therefore no topping up is required and formation of
hydrogen gas is suppressed. Under normal float conditions,
approximately 95 to 99 percent of hydrogen and oxygen is recombined.
In 1994 the VRLA batteries
were introduced in Indian Telecom Network for the first time. Since then, the
Department has been procuring VRLA batteries for the purpose.
This is because of the fact
that these batteries do not require the rigid routine maintenance like periodic
topping up, recording SG of each cell and periodic discharge/charge cycles.
VRLA batteries require very
little maintenance that is why they are confused as “maintenance free
batteries”. These batteries emit extremely low amount of gases and do not require
periodic toping up. Hence, they can be
installed in the equipment room itself, thus saving the manpower and long
connecting bus-bar or cables. Plates of these batteries have a higher
current density, hence have a small size. As these batteries are based on
starved electrolyte principal, can be installed in any orientation. All the
above characteristics make VRLA batteries ideal stand by power source for
Telecom applications.
But
these batteries have their own problem and limitation, which require timely and
intelligent handling. Some of the constraints are :
Self Discharge : As these batteries are supplied in charged condition.
These cells/batteries get discharged of its own on its internal resistance and
some localised action within the cells. This is termed as self discharge. Self
discharge of these cells/batteries is about 14 percent every four weeks. If
these cells/batteries are allowed to remain in this state for a long period of
time, say, 3 months or more, the sulphation of the plates starts setting in.
More the time it is allowed to remain in this state, more the sulphation gets
hard and more it becomes difficult to remove it from cells/batteries.
It is essential that these
cells/batteries are commissioned in the least possible time so that self
discharge and subsequent sulphation layer is kept to minimum.
Temperature
Effect : Batteries are very temperature sensitive. The kinetics of
these batteries are temperature dependent. The chemical reaction
increases/decreases in geometric progression which the increases or decrease in
temperature. The Temperature in case of VRLA Batteries is significant because
of limited volume of electrolyte which restricts heat conduction. In the light
of this fact, the proper temperature is essential for the optimization of
battery life. Internationally the batteries are design at 25 deg Celsius or 27
deg Celsius. The recombination of gases within a VRLA cell can only take place
at a certain rate. If the rate is exceeded, gas pressure will built up beyond
the safety valve level, and gases/water will be vented out and permanently
lost.
The highest float voltage at
which a cell still recombine all the gases driven off the plates is
approximately 2.30Volts. If the cell temperature increased while holding the
voltage constant, the cell would dry out and possibly go into thermal runaway.
Thermal runaway leads to a melting down of the jar and under worst- case
scenario, will lead to an explosion and fire.
a) Low
Temperature effect : Battery capacity is diminished at low temperature. Also
the charge acceptance decreases with the decrease in temperature. Therefore at
low temperatures, a higher float voltage is required to maintain full charge
and if charger is not adjusted properly, cell may be undercharged, leading to
the problems described under low voltage.
b) High
Temperature effect : The chemical reaction becomes faster and faster with rise
in temperature above the design temperature (27 degree Celsius) and give rise
to a chain reaction. High temperature causes loss of life because every 10 deg
Celsius rise in operating temperature, the life is cut to half. High
temperature also causes gassing, which means dry out and thermal runaway in
VRLA cells.
Recommendation
:
i) Batteries
temperature shall be maintained to such a value that it does effect the life
and performance of the battery i.e. the average temperature shall be maintained
around the designed temperature at 35°C.
ii) Charging voltage shall be such that it does not
contribute to rise in temperature i.e. 2.25V for float and 2.30 for charge.
iii) The charging
current to the battery may be restricted to defined limit ( 0.1C recommended).
iv) A provision shall be made so that the charger voltage
shall be regulated as per battery temperature to slow down the battery
kinetics. The provision for battery temperature compensation has been made in
the Power Plants. It may be ensured that Battery Temperature compensation unit
in the power plant is fully functional & all the terminations are in proper
place.
v) Though not
mandatory, it is preferable that the battery may be installed in controlled
environment for longer life and better performance.
Failure of VRLA batteries : Most
common reasons for failure of VRLA batteries are :
Positive grid corrosion : Every time battery discharges, PbO2 of the +ve plate
gets converted into PbSO4 there is a large increase in its volume, which puts
pressure on the paste. Deeper the discharged, more is the increase in the
volume of the paste of the positive plate and more is the pressure on the grid.
During charge the
paste of the +ve gets converter back into PbO2 The paste gets contracted.
This
expansion and contraction results in loosening of the active material in the
grid, over a period of time. This results in loss of contact of the active
material with the +ve plate and increase in the cell resistance.
This is
a gradual process and under normal circumstances is a sign of ageing, which
shall only take place when the battery has lived its stipulated life.
In addition to ageing
there are other factors which accelerate the process and lead to premature
ageing. Some of them are :
1. Larger number of charge/discharge cycles faster the ageing process.
2. Deep Discharge, deeper the discharge faster the ageing.
3. Fast rate of Charging.
4. Fast rate of Discharging.
Corrosion is
un-recoverable and indicates the end of cell life.
Sulphation : Sulphation of the cells plates due to prolonged under
charge, overcharge or prolonged storage may also increases the cell resistance.
This is a recoverable
damage unless it is hard enough to remove and can be recovered by careful and
controlled charging of the cell. In case the sulphation is soft (not very
thick), the same may be recovered by charging the cell along with the battery.
The medium type of
sulphation can also be removed by prolonged charging, which may be complete or
part depending on hardness of the sulphation.
In both the above
cases a few charge/discharge cycles are required for the optimum recovery.
This may be achieved by
cycling the cell inside the battery or removing the cell from battery bank and
reconditioning, special treatment of charging etc. at the factory by the
manufacturer at his premises.
Some times sulphation
becomes too hard to overcome. In such a case cell is supposed to be damaged
beyond repair.
Dry out (loss electrolyte) : There is a misconception that these batteries are
fully sealed and no escape of gasses take place. However, the gasses escape
through the safety valve to maintain the pressure within cells in prescribed
limits and therefore, most common mode of failure of the cell/battery is dry
out. This may happen due the excessive escape of gasses from the cell, which
leaves the cell with little or no electrolyte. This may happen due to :
a) Fast charging
b) Operation of the battery at a very high temperature
c) Leakage through cracks in the container or sealing.
Thermal Runaway : Batteries are very temperature sensitive. The
chemical reaction increases/decreases in geometric progression with the
increases or decrease in temperature. The Temperature in case of VRLA Batteries
is significant because of limited volume of electrolyte which restricts heat
conduction. In the light of this fact, the proper temperature is essential for
the optimization of battery life. The recombination of gases within a VRLA cell
can only take place at a certain rate. If the rate is exceeded, gas pressure
will built up beyond the safety valve level, and gases/water will be vented out
and permanently lost.
The highest float
voltage at which a cell still recombine all the gases driven off the plates is
approximately 2.30Volts. If the cell temperature increased while holding the
voltage constant, the cell would dry out and possibly go into thermal runaway.
Thermal runaway leads to a melting down of the jar and under worst- case
scenario, will lead to an explosion and fire.
In the initial stage
of VRLA battery development of thermal runaway was considered one of the
failure mode, but in India it has not been observed till date and moreover at
present it is not considered failure mode. Thermal runaway is calliopes of the
battery due to very very high temperature developed inside the battery.
Recommendation :
i) The SMPS Power plants are fully compatible to prevent any excessive
temperature in the battery by the features Battery path current limiting,
Temperature compensation of the battery, High voltage cut-off and Precise
voltage set in the Power Plant.
ii) The user shall ensure that all the above features of SMPS Power Plants
are fully functional and properly set.
iii) The battery room shall be employed with the natural air convection
(ventilated room) and exhaust fan.
iv) The user shall
ensure that the ambient temperature of the battery room has been reduced by
employing the natural air convection (ventilated room) with exhaust fan.
Factors leading to the premature failure
and affecting the life & performance of the battery : Some of the common factors which affect
the premature failure and affecting the life & performance of the battery
are :
a) Battery discharge
: The battery shall not be allowed to
discharge beyond 80% of its rated capacity.
b) Improper Charging
: Under ideal conditions i.e.
moderate ambient temperature (10°C to 35°C), Charging not faster than C/10
rate, and compatible charger a telephone exchange battery, on true float may
give about 15 years of its service life, The same battery in cyclic discharge
application to 80% DOD (Depth of discharge) will give only 1400 cycles i.e.
Four year approximately. The battery application in Indian Telecom Network is
neither of the two extreme categories. So more the deep discharge cycles/year,
lesser the expected life of the battery.
The faster the rate of discharge of a battery lower is its expected
life for example discharging battery at C/1 rate of discharge will give just
half the number of DOD cycles than the battery which is discharged at C/8 or
C/10 rate of discharge.
i)The exchange/transmission & similar application batteries shall
be so chosen that they are not allowed to discharge faster than C/6.
ii) Where faster discharge( C/0.5 to C/5) is an essential requirement,
as in the case of UPS systems etc., the battery may be planned with the lower
expected life as per the rate of discharge.
c) No Temperature control : Batteries are very temperature sensitive.
The kinetics are temperature dependent. The chemical reaction
increases/decreases in geometric progression with the increases or decrease in
temperature. The proper temperature will optimize battery life and is
especially critical for VRLA Battery. The recombination of gases within a VRLA
cell can only take place at a certain rate. If the rate is exceeded, gas
pressure will built up beyond the safety valve level, and gases/water will be
vented out and permanently lost. At 27 deg Celsius, the highest float voltage
at which a cell still recombine all the gases driven off the plates is
approximately 2.30Volts. If the cell temperature increased while holding the
voltage constant, the cell would dry out and possibly go into thermal runaway.
Thermal runaway leads to a melting down of the jar and under worst- case
scenario, will lead to an explosion and fire.
a) Effect of Low Temperature :
Battery capacity is diminished at low temperature. Also the charge acceptance
decreases with the decrease in temperature. Therefore at low temperatures, a
higher float voltage is required to maintain full charge and if charger is not
adjusted properly, cell may be undercharged, leading to the problems described
under low voltage.
b) Effect of High Temperature :
The chemical reaction becomes faster and faster with rise in temperature above
the design temperature ( 27° Celsius) and give rise to a chain reaction. High
temperature causes loss of life because every 10° Celsius rise in operating
temperature, the life is cut to half. High temperature also causes gassing,
which means dry out and thermal runaway in VRLA cells.
Recommendation :
i) Ensure that battery temperature compensation in the power plant is
fully functional & all the terminations are in proper place.
ii) Do not resort to fast charging by setting higher float/charge
voltages.
iii) Though not mandatory it is advisable to place the batteries in
cooler environment for longer life and better performance.
d) Cell Matching
e) Storage of VRLA Batteries
f) Improper installation
g) Manufacturer Problems
h) Operational/Maintenance issues.
The VRLA batteries for slow discharge
application (Discharge rate C/6 to C/120) GRs No. GR/BAT-01/03 MAR 2004 and
GR/BAT-03/01 MAR 2006 with Amendments if any
: Table-1
|
Rate of Discharge
|
Cell
|
Mono-Block
|
Discharge
Current
|
Capacity expressed as % of C/10
Discharge rate
|
Discharge
time (min)
Minutes
|
End cell voltage
|
Discharge Current
|
Capacity expressed as % of C/10
Discharge rate
|
Discharge
time (min)
Minutes
|
End cell voltage
|
C/3
|
0.333C
|
71.7
|
129
|
1.74V
|
0.333C
|
75.0
|
135
|
10.44V
|
C/4
|
0.25C
|
78.2
|
188
|
1.74V
|
0.25C
|
81.0
|
195
|
10.44V
|
C/5
|
0.2C
|
83.3
|
250
|
1.75V
|
0.2C
|
85.0
|
255
|
10.5V
|
C/6
|
0.167C
|
87.3
|
314
|
1.75V
|
0.167C
|
91.0
|
328
|
10.5V
|
C/8
|
0.125C
|
95.0
|
456
|
1.75V
|
0.125C
|
95.0
|
456
|
10.5V
|
C/10
|
0.1C
|
100-120
|
600-720
|
1.75V
|
0.1C
|
100-120
|
600-720
|
10.5V
|
C/20
|
0.05C
|
120.0
|
1440
|
1.75V
|
0.05C
|
120.0
|
1440
|
10.5V
|
C/72
|
0.014C
|
130.0
|
5616
|
1.75V
|
0.014C
|
130.0
|
5616
|
10.5V
|
C/120
|
0.0083C
|
150.0
(SPV Application only)
|
10800
|
1.75V
|
0.0083C
|
150.0
(SPV Applicationonly)
|
10800
|
10.5V
|
The VRLA batteries for high rate of
discharge (UPS) application (Discharge rate C/0.5 to C/5) GR No. GR/BAT-02/02
MAR 2006
: Table-2
|
Rate of Discharge
|
Cell
|
Mono-Block
|
Discharge
Current
|
Capacity
expressed
as % of C/5
Discharge
rate
|
Discharge
time (min)
Minutes
|
End cell voltage
|
Discharge
Current
|
Capacity expressed as %
of C/5
Discharge rate
|
Discharge
time (min)
Minutes
|
End
mono-
block voltage
|
C/0.5
|
2*C
|
45
|
13.5
|
1.70V
|
2*C
|
50
|
15
|
10.2V
|
C/1
|
1*C
|
60
|
36
|
1.70V
|
1*C
|
65
|
39
|
10.2V
|
C/2
|
0.5*C
|
81
|
97
|
1.70V
|
0.5*C
|
85
|
102
|
10.2V
|
C/3
|
0.33*C
|
86
|
155
|
1.74V
|
0.33*C
|
91
|
164
|
10.44V
|
C/4
|
0.25*C
|
95
|
228
|
1.75V
|
0.25*C
|
96
|
231
|
10.5V
|
|
|
|
|
|
|
|
|
|
|
The battery gives rated
capacity only at the discharge rate for which it is designed. For example VRLA
batteries for Telecom applications as per GRs No. GR/BAT-01/03 MAR 2004 and
GR/BAT-03/01 MAR 2006 with amendments if any are designed at C/10 (0.1*C) rate
of discharge. The VRLA batteries as per GR No. GR/BAT-02/02 MAR 2006 are
designed at C/5 rate of discharge and will give rated capacity only when it is
discharged at a discharge current equal to 0.2*C. At all other discharge rates
faster than the 10 hours or 5 hour rate as the case may be the battery will
deliver less than its rated capacity. Faster the rate of discharge lower the
capacity the battery will deliver. The relation between rate of discharge and
expected capacity is as given in tables 1& 2 above.
As per the table-1 given
above, when the battery is discharged at a current equal to 0.33 times its
rated capacity to the end cell voltage of 1.74V/cell, will be only 71.7% of the
rated capacity and last for 129 minutes instead of 180 minutes as anticipated.
In case the discharge current is equal to 0.2 time its rated capacity the
battery will be 83.3% of its rated capacity and last for about 250 minutes
instead of 300 minutes and so on.
The temperature at which the battery is
to work : At temperature lower than
27° Celsius the capacity of the battery is reduced by 0.5% with every one
degree decrease in temperature. This factor is of relevance at places where the
ambient temperature goes very low (below 5 degree Celsius) and the rate of
discharge is also low, less than C/20.
Charging of battery at rates faster than
C/10 is not recommended : As the
faster rate of charging is not recommended for VRLA batteries, it is essential
that the power plant shall be programmed to ensure that current allowed to
battery is restricted to 10% of its rated capacity. For this purpose the
proposed battery capacity is essential for battery path current limit setting.
Sample Calculation 1 : Switching System
:
(Slow Discharge Application (Battery
back-up 6 hours & higher)
Data Required :
a) Load Present : 400A …. Say
Ultimate : 700A
b) back-up required : 6 hours
c) Permissible DOD : 80%
Battery Capacity Calculations :
- As the battery is for slow discharge application, - The Battery is
expected to deliver the effective capacity of 87.3% of C/6 rate at discharge
rate of C/10 as indicated in the given table -1.
The required capacity of the battery, considering all the above factors
can be calculated as given below :
At present : 400*(6/0.8)/0.873 = 3436.4 AH
Ultimate : 700*(6/0.8)/0.873 = 6013.7 AH say 6000 AH
The battery-bank can
be formed by selecting available batteries. The solution in this case is : two
2000AH batteries for the present load and additional 2000AH battery can be
added at the later stage.
Sample Calculation 2 : Computer Terminal :
(High discharge application (Battery back-up 0.5 to 5
hours)
Data Required :
a) Load Present : 50A ….
Say
Ultimate : 80A
b) Back-up required : 0.5
hours
c) Permissible DOD : 80%
Battery Capacity
Calculations :
- As the battery is for
high discharge application, Battery is
expected to deliver the effective capacity 45% at C/0.5 rate of discharge of
C/5 as indicated in the given table - 2 on page 26.
The required capacity of
the battery, considering all the above factors can be calculated as given below
:
At present :
50*(0.5/0.8)/0.45 = 69.44AH
Ultimate :
80*(0.5/0.8)/0.45 = 111.11AH
The battery-bank can be
formed by selecting available batteries. The solution in this case is : one
80AH battery for the present load and additional 80 AH battery.
Terminology
Absorption : The
taking up or retention of one material or medium by another by chemical or
molecular action.
Activated Stand Life : The period of time, at a specified temperature, that
a cell/mono-block/battery can be stored in the charged condition before its
capacity falls below a specified level.
Activation :
The process of making a reserve cell/mono-block/battery function.
Ageing :
Permanent loss of capacity due to either repeated use or the passage of time.
Ambient Temperature : The average temperature of the surroundings.
Ampere-Hour (AH) Rating : The rating assigned to the cell/mono-block shall be the
capacity expressed in ampere-hours (after correction at 27° Celsius) and stated
by manufacturer to be obtainable when the cell/mono-block is discharged at 5
hour rate (C/5) to a final end voltage of 1.75V/cell or 11.5V/mono-block.
Ampere-hour Efficiency : The percentage ratio of the output of the secondary
cell or mono-block or battery, measured in ampere-hours, to the input required
to restore the initial state of charge, under specified conditions.
Available Capacity : The total capacity, AH or WH, that will be obtained from a cell,
mono-block or battery at defined discharge rate and other specified discharge
rates or operating conditions.
Capacity :
The total number of ampere-hours or watt hours that can be withdrawn from
a fully charged cell,
mono-block or battery under specified conditions or discharge.
Capacity Fade :
Gradual loss of capacity of a secondary battery with cycling.
Capacity Retention : The fraction of the full capacity available from a battery under
specified conditions of discharge after it has been stored for a period of
time.
Charge Acceptance : Willingness of a battery or cell or mono-block to accept charge. It is
affected by cell/mono-block temperature, charge rates and state of charge.
Closed Circuit Voltage (CCV) : The difference in potential between the terminals of
a cell/mono-block or battery when it is discharging.
Conditioning :
Cycle charging and discharging of a battery to ensure that it is fully formed
& fully charged. Sometimes indicated when a battery is first placed in
service or returned to service after prolonged storage.
Constant Current Charging : A method of charging the battery using a current
having little variation.
Constant Voltage Charging : A method of charging the battery by applying a fixed
voltage, and allowing variations in the current. Also called constant potential
charge.
Continuous Test : A test in which a cell/mono-block or battery is discharged to a
prescribed end-point voltage without interruption.
Counter Electromotive Force : A voltage opposing the applied voltage. Also referred
to as Back EMF.
Current Density : The current per unit active area of the surface of an electrode.
Cut-off Voltage : The cell/mono-block or battery voltage at which the discharge is
terminated. It is also called end voltage.
Cycle : The discharge and subsequent or preceding charge of a
secondary battery such that it is restored to its original conditions.
Cycle Life :
The number of cycles under specified conditions which are available from a
secondary battery before it fails to meet specified criteria of performance.
Deep Discharge : Withdrawal of at least 80% of the rated capacity of a cell, mono-block
or battery.
Depth of Discharge (DOD) : The ratio of the quantity of electricity (usually in
ampere-hours) removed from a cell or battery on discharge to its rated
capacity.
Efficiency :
The ratio of the output of a secondary cell or battery to the input required to
restore it to the initial state of charge under specified conditions.
Electrolyte :
The medium which provides the ion transport mechanism between the positive and
negative electrodes of a cell/mono-block.
End Voltage :
The prescribed voltage at which the discharge (or charge, if end-of-charge
voltage) of a cell/mono-block or battery may be considered complete (also cut
off voltage).
Energy Density : The ratio of the energy available from a cell/mono-block or battery to
its volume (WH/V). Also used on a weight basis (WH/Kg).
Fast Charge :
A rate of charging which returns full capacity to a rechargeable battery,
usually within an hour.
Float Charge :
A method of maintaining a cell/mono-block or battery in a charged condition by
continuous, long-term constant-voltage charging, at a level sufficient to
balance self-discharge.
Gas Recombination : Method of suppressing hydrogen generation by recombining it with
oxygen on the negative electrode, as the cell approaches full charge.
Half-Cell :
An electrode (either the anode or cathode) immersed in a suitable electrolyte.
Hourly Rate :
A discharge rate, in amperes, of a cell/mono-block or battery which will
deliver the specified hours of service to a given end voltage.
Internal Resistance : The opposition or resistance to the flow of an
electric current within a cell or battery. It is the sum of the ionic and
electronic resistances of the cell/mono-block components.
Life : For
rechargeable batteries, the duration of satisfactory performance, measured in
years float life) or in the number of charge/discharge cycles (cycle life).
Load : The
term used to indicate the current drain.
Lot : All
batteries of the same type, design and rating, manufactured by the same factory
during the same period, using the same process and material, offered for
inspection at a time shall constitute a lot.
Maintenance-Free Battery : A secondary battery which does not require periodic
"topping up" to maintain electrolyte volume.
Memory Effect :
A phenomenon in which a cell, operated in successive cycles to the same, but
less than a full, depth of discharge experiences a depression of its discharge
voltage and temporarily loses the rest of its capacity at normal voltage
levels.
Open-Circuit Voltage (OCV) : The potential or voltage of a cell/mono-block or
battery when it is at the surface of the electrode.
Overcharge :
The forcing of current through a cell/mono-block after all the active material
has been converted to the charged state. In other words, continued charging
after 100% state of charge is achieved.
Over discharge : Discharge past the point where the full capacity of the
cell/mono-block has been obtained.
Over voltage :The
potential difference between the equilibrium potential of an electrode and that
of the electrode under an imposed polarisation current.
Oxygen Recombination : The process by which oxygen generated at the +ve
plate during charge is reacted at the -ve plate.
Parallel :
Term used to describe the interconnection of cells or batteries in which all of
the like terminals are connected together. Parallel connections increase the
capacity of the resultant battery as follows :
Cp = n X Cu ; Where Cp
is the resultant capacity, n is the number of cells or batteries connected in
parallel & Cu is capacity of the each cell or battery.
Rated Capacity : The number of ampere-hours a cell/mono-block or battery can deliver
under specific conditions (rate of discharge, end voltage, temperature):
usually the manufacturer's rating.
Recombination :
A term used in a sealed cell construction for the process whereby internal
pressure is relieved by reaction of oxygen with the negative active material.
Reference Electrode : A specially chosen electrode which has a reproducible
potential against which other electrode potentials may be referred.
Self-Discharge : The loss of useful capacity of a cell/mono-block or battery due to
internal chemical action (local action).
Semi-Permeable Membrane : A porous film that will pass selected ions.
Separator :
An ion permeable, electronically non-conductive, spacer or material which
prevents electronic contact between electrodes of opposite polarity in the same
cell.
Series : The
interconnection of cells/mono-blocks or batteries in such a manner that the
positive terminal of the first is connected to the negative terminal of the
second, & so on. Series connections increase the voltage of the resultant
battery as follows :
Vs = n X Vu Where Vs
is the resultant voltage, n is the number of cells/mono-blocks or batteries
connected in series & Vu is voltage of the each cell/mono-block or battery.
Service Life :
The period of useful life of a cell/mono-block or battery before a
predetermined end-point voltage is reached.
Shelf Life :
The duration of storage under specified conditions at the end of which a
cell/mono-block or battery still retains the ability to give the specified
performance.
Short Circuit Current : The initial value of the current obtained from a
cell/mono-block or battery in a circuit of negligible resistance.
Specific Gravity : The specific gravity of a solution is the ratio of the weight of the
solution to the weight of an equal volume of water at a specified temperature.
Standby Battery : A battery designed for emergency use in the event of a main power
failure.
Starved Electrolyte Cell : A cell containing little or no free fluid
electrolyte. This enables gases to reach electrode surfaces during charging and
facilitates gas recombination.
State-of-Charge (SOC) : The available capacity in a cell/mono-block or
battery expressed as a percentage of rated capacity.
Sulphation :
Process occurring in lead batteries that have been stored & allowed to
self-discharge for extended periods of time. Large crystals of lead sulphate
grow and interfere with function of the active materials.
Thermal Runaway : A condition whereby a cell/mono-block or battery on charge or
discharge will overheat and destroy itself through internal heat generation
caused by high overcharge or over discharging current or other abusive
condition.
Trickle Charge : A charge at a low rate, balancing losses through a local action and/or
periodic discharge, to maintain a cell/mono-block or battery in a fully charged
condition.
Vent : A
normally sealed mechanism which allows for the controlled escape of gases from
within a cell/mono-block.
Vented Cell/mono-block : A cell/mono-block design incorporating a vent mechanism
to relieve excessive pressure and expel gases that are generated during the
operation of the cell/mono-block.
Voltage Delay : Time delay for a cell/mono-block or battery to deliver the required
operating voltage after it is placed under load.
Voltage Efficiency : The ratio of average voltage during discharge to average voltage
during recharge under specified conditions of charge and discharge.
Watt Hour (WH) Capacity : The quantity of electrical energy measured in watt
hours which may be delivered by a cell/mono-block or battery under specified
conditions.
Watt Hour (WH) Efficiency : The ratio of the watt hours delivered on discharge of
a battery to the watt hours needed to restore it to its original state under
specified conditions of charge and discharge. The percentage WH efficiency is
the product of AH efficiency & the ratio of average discharge and recharge
voltage.
Wet Shelf Life : The period of time that a cell/mono-block or battery can stand in the
charged or activated condition before deteriorating below a specified capacity.
Working Voltage : The typical voltage or range of voltage of a cell/mono-block or
battery during discharge.
The ventilation requirements for battery
rooms as recommended in various applicable standards
are given below.
Table
1: Ventilation Requirements
Applicable
Standard
|
Battery room Ventilation
Requirements
|
NFPA 76
|
The battery room exhaust fan capacity in Cubic Feet
Minute
(CFM) should be the
room area (in square foot)
|
Tamil Nadu Factory
Rules, 2002
|
The air exchange
(fresh air for one air) for a general factory shall be six times the cubic
capacity of the work room without dead pockets or undue draught
|
ASHRAE 62
|
1 CFM per charging ampere to be provided but not less
than 6 air
changes per hour
|
IS :12332
|
• 12 air changes per hour for battery room
• Forced air supply & positive exhaust system
• Use of flameproof electrical fittings
• Air inlets to be located near the floor &
outlet openings at the
high point in the
room
Although
this standard is for industrial environment, the
recommendations can logically be extended to all
battery rooms.
|
Document on Battery
Rooms by EXIDE
Technologies
EN 50272-2 - Safety
requirements for
Secondary Batteries
and Battery
Installations
|
Volume of Air Changes per Hour:The following formula
is to calculate the hourly exchange of air volume,
Q in Cubic
Meters / hour recommended for battery rooms.
Q = 0.05 x n x I
(cubic meter / hour)
Where:
n = number of cells
I = Value for the current from table
of EN 50272-2
Minimum Inlet & Outlet Area (A):
With natural ventilation, the minimum inlet and
outlet area is
calculated as follows:
A should be greater than or equal to 28 x Q (sq.
cm)
|
Way of air
circulation in battery rooms:
Table
2 : Recommended Layout Features of UPS Rooms
Design
Aspects
|
Recommended
Considerations
|
Installation
|
The electrical installation in battery rooms should
be limited to:
• Lighting
• Charging facilities
• Ventilation
• Hoisting &
lifting provisions
|
Smoke / Gas
Detection
|
Smoke detectors may be installed in battery rooms.
In rooms where
vented type lead acid batteries are installed,
Hydrogen detectors may
be installed. Fan operation may be interlocked with
Hydrogen detector
actuation. If Hydrogen detectors are not installed,
the fan shall run
continuously.
|
Battery Room
Ceiling
|
Preferably the room ceiling should be flat to ensure
that pockets of
trapped Hydrogen gas do not occur, particularly at
the ceiling, to
prevent the
accumulation of an explosive mixture, as per NFPA 70 E- 83.
|
Ventilation
|
Refer the table 1
for details. A back up fan also may be considered.
|
Fire Protection
|
Carbon Dioxide
portable fire extinguishers to be provided.
|
Lighting
|
Light fittings
should be fixed to the wall or suspended at more than 50 cm from the ceiling,
but not vertically above the batteries or charging units. Light fittings as
well as any other equipment should be of closed type to prevent accumulation
of gas. However, watertight fittings, with flameproof construction are
recommended because of possible corrosive & flammable gas environment.
|
For VRLA batteries,
optimal gas recombination is a function of operating temperature.
Heat generated during
charging
Float mode the heat
generation in watt-hrs
= 0.1 x 2.23 x Ah @
C10 x No. of cells in the battery bank / 100
Boost mode the heat
generation in watt-hrs
= 0.2 x 2.3 x Ah @ C10
x No. of cells in the battery bank / 100
The VRLA batteries do
not have their own mechanism to remove heat, hence requires skin cooling
mechanism.
The UPS system is
designed to operate continuously at full load without degradation of its
reliability, operational characteristics or
service life in following environmental condition:
UPS Ambient
temperature 00C to 400C
Battery Ambient
temperature 270C
Humidity upto 95%
RH non-condensing
The UPS has its own
fan to remove heat from semiconductor devices and dissipate out side the
enclosure into room, proper mechanical ventilation is required to remove heat
to atmosphere.
Tabular comparison of Batteries based on
different technologies (VRLA
AGM, Tubular VRLA GEL and Flooded)
S.
No.
|
Feature
|
VRLA (AGM)
|
Tubular GEL VRLA
|
Tubular Flooded
|
1.
|
Gassing/
fuming
|
No gassing/fuming, can be installed anywhere
|
No gassing/fuming, can be installed anywhere.
|
High gassing/fuming, separate battery room with
exhaust system is essential.
|
2.
|
Topping up of electrolyte
|
No topping-up required normally
|
No topping-up required normally
|
Topping up required frequently
|
3.
|
Charging current level
|
High
|
Lower
|
Lowest
|
4.
|
Space requirement
|
Small cell size, Low space requirement.
|
Small cell size, Low space requirement.
|
Large cell size, Large space required.
|
5.
|
Stacking
|
Horizontal or vertical
|
Up to 1500 AH : Horizontal or vertical
>1500 AH: Vertically, in tiers
|
Vertical stacking only. Tier stacking not practical
for large size.
|
6.
|
Transportation in charged condition
|
Easy
|
Easy
|
Not possible. Transportation in uncharged (unfilled)
condition recommended.
|
7.
|
Self-discharge during storage, at an average
temperature of 35°C.
|
50% self-discharge in 6 months. Recovery easy.
|
50% self-discharge in one year. Recovery easy.
|
Self-discharge is very high. Long duration storage
not recommended. Recovery difficult.
|
8.
|
Cyclic Life
(to 80% DoD).
|
1400 cycles at an average temperature of 35°C in
normal environmental condition
|
Better than 2100 cycles at an average temperature of
35°C in normal environmental condition
|
Theoretically maximum 2000 cycles at 27°C.
|
9.
|
Float life at 35°C.
|
Good
|
Good
|
Not known
|
10.
|
High temperature performance
|
Average, but temperature compensation provision made
in the Power Plants
|
Good
|
Good
|
11.
|
Low temperature performance
|
Good
|
Good
|
Poor
|
12.
|
Stratification
|
Negligible, no boost charging required.
|
Negligible, no boost charging required.
|
Prominent, requires frequent boost charging for
prevention.
|
S. No.
|
Feature
|
VRLA (AGM)
|
Tubular GEL VRLA
|
Tubular Flooded
|
13.
|
End cell voltage
|
1.75V/cell
|
1.75V/cell
|
1.85V/cell
|
14.
|
Capacity at very low rate of discharge
|
Good
|
Good
|
Average
|
15.
|
Deep discharge recovery
|
Average, after 4 to 5 charge/discharge cycles
|
Average, after 4 to 5 charge/discharge cycles
|
Poor, hard sulphation prevents recovery.
|
16.
|
Charge efficiency
|
Excellent, 6 to 8 hours for 90% recovery.
|
Slightly poor, 8 to 10 hours for 90% recovery
|
Poor, 12 to 14 hours for 90% recovery.
|
17.
|
Under-charged performance
|
Average
|
Good
|
Poor
|
18.
|
Overcharging
|
Poor, damages the battery.
Over charge protection provision
made in SMPS Power Plants.
|
Good
|
Good
|
19.
|
Performance under partial
state of charge
|
Good
|
Good
|
Poor
|
20.
|
Charging Requirement
|
Constant voltage charging
by SMPS Power plants
|
Constant voltage charging
by SMPS Power plants
|
Periodical boost charging
at 2.7V/cell essential
|
21.
|
Thermal runaway
|
Probable, yet rare
|
Not possible
|
Not found
|
22.
|
Risk of internal
short-circuiting
|
Remote
|
Remote
|
High, due to active
|
Design and
Construction:
Positive
Plate: Flat pasted type with
Lead-calcium High Tin alloy grid to resist corrosion & longer life.
Negative
Plate: Flat pasted type with
Lead-calcium alloy grid for maintenance free characteristics
Container: High impact Polypropylene co-polymer, ribbed jar
design for better heat dissipation and strength. Flame-retardant polypropylene
UL 94 V 0/28% LOI is optional
Separator: Low resistance, high porosity and highly absorbent
type glass mat separator (AGM) Oxygen & hydrogen are recombined internally
to form water.
Electrolyte: High purity Sulphuric acid to maximize shelf life. Electrolyte
is immobilized (not allowed to flow).
Terminals: Lead plated Copper inserts for high conductivity
Safety
Valve: Self resealing, pressure
regulated and explosion proof
Container
and cover sealing: Heat Sealing Method
for better joint strength
Operation:
Type of
charging: Constant potential, current
limited to 10% of the rated capacity (0.2 C 10 Amp)
Float
Voltage: 2.25+/- 0.01 VPC at 27 0C
Boost
Voltage: 2.30 +/- 0.01 VPC at 27 0C
AC Ripple: Ripple content shall not exceed 3% RMS
Performance:
Float life: 20 years designed life at 27O C on full
float with recommended charging methods
Cyclic life
at 27O C:
1200 cycles at 80% Depth of Discharge
2000 cycles at 50% Depth of Discharge
4000 cycles at 20% Depth of Discharge
Design life
– is used by manufacturers as a
measure of comparison. It is a theoretical figure.
It is used as a short-hand method of comparison, as in
“5-year,” “10-year,” and “20-year”
battery, and is the basis for pro-rated warranties
Service life
- is the more realistic time (in
years) from the installation of the battery until its
capacity falls below 80% of its nominal rating.
Service life implies a replacement interval
shorter than the design life. In practice, the end of
useful life for VRLA batteries can be as
much as 50% below its design life. In extremely harsh
operating environments life as low as
20% have been reported. When properly applied,
monitored and cared for, VRLA batteries
frequently achieve 70-80% of design life.
Cycle Life
A battery that is seldom used will obviously last
longer than a battery that is discharged and recharged every day. Every time
you pull voltage out of a battery you discharge it. The amount of watts and the
length of time you discharge determine the “depth of discharge” (DOD). The rate
at which you pull watts out of a battery, the amount of recharge time between
discharges, and the rate of recharge are also important. Battery designs generally
assume 2-3 deep discharges per year (100% depth of discharge). As a general
rule, a VRLA battery can provide hundreds of shallow discharges (e.g., <25%
DOD). Actual field experience will include a wide variety of cycle conditions.
High Ambient
Temperature
Battery manufacturers usually describe their warranted
or design life in terms of years operating at a particular ambient temperature.
In controlled environments reasonable predictions can be made. The rule of
thumb for a stationary VRLA battery kept at a constant state of charge (float
life) says there is a 50% reduction in life for every 8°C (14.4°F) increase in
temperature above optimum 25°C (77 °F). VRLA batteries have gotten a lot of bad
press due in part to their widespread use in confined and uncontrolled environments
such as outdoor cabinets where wide extremes of temperature are common. The
graph in Figure 1 gives a reasonable service life expectancy for continued
operation at stable temperatures such as expected in a data center.
Rules of thumb come with many disclaimers. Figure 1
addresses only one variable (temperature), but VRLA batteries are affected by
many variables. For example, even though room temperature may be optimum, batteries
packed tightly together or stuffed into unventilated cabinets may actually
experience a higher internal temperature leading to premature capacity loss.